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CAS.192198-85-9 TPBi

1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene
CAS.192198-85-9  TPBi

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1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene Basic information
Applications
Product Name: 1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene
Synonyms: 1,3,5-TRIS(1-PHENYL-2-BENZIMIDAZOLYL)BENZENE;TBPI;1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene;1,3,5-Tris(N-phenylbenzimidazol-2-yl)benzene;2,2',2''-(1,3,5-Benzenetriyl)tris[1-phenyl-1H-benzimidazole];TPBi;2,2',2" -(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole);1,3,5-Tri(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl
CAS: 192198-85-9
MF: C45H30N6
MW: 654.76
EINECS: 1312995-182-4
Product Categories: OLED;oled materials
Mol File: 192198-85-9.mol
1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene Structure
 
1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene Chemical Properties
Melting point  272-277°C
density  1.26
storage temp.  Keep in dark place,Sealed in dry,Room Temperature
solubility  DMSO (Slightly), Methanol (Slightly)
pka 4.25±0.10(Predicted)
form  powder
λmax 302nm(CH2Cl2)(lit.)
InChIKey GEQBRULPNIVQPP-UHFFFAOYSA-N
SMILES C1(C2N(C3=CC=CC=C3)C3=CC=CC=C3N=2)=CC(C2N(C3=CC=CC=C3)C3=CC=CC=C3N=2)=CC(C2N(C3=CC=CC=C3)C3=CC=CC=C3N=2)=C1
Absorption λmax?305 nm?in THF
color  White Powder
 
Safety Information
Risk Statements  36/37/38
Safety Statements  26-36/37/39
HS Code  29339900
MSDS Information
 
 
1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene Usage And Synthesis
Applications 2,2',2"-(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole), TPBi, being electron deficient, is normally used as electron transport layer material in optoelectronic devices. Having a low LUMO energy level (2.7 eV), TPBi is also used as host material for both fluorescent and phosphorescent light emitting systems.
In some cases, TPBI is used to replace CBP (HBL)/Alq3 (ETL) to simplify the device structure for its excellent electron transporting and also its hole blocking abilities with very deep HOMO energy level (HOMO = 6.2/6.7 eV). It has also been reported that TPBi could be used as electron injection layer material between Alq3 (ETL) and Cs2O3/Al (electrode). It suggested that TPBI thin layer at the Alq3/Cs2O3 interface facilitates the electron injection and is also involved with hole-blocking and exciton confinement.
Description 2,2',2''-(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole), TPBi, being electron deficient, is normally used as electron transport layer material in optoelectronic devices.?Having a low LUMO energy level (2.7 eV), TPBi is also used as host material for both fluorescent and phosphorescent light emitting systems.
Uses Used in OLED′s devices as electron transport and exciton blocking materials.

 

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